ENVIRONMENTAL MANAGEMENT FRAMEWORK THAILAND HCFC PHASE-OUT PROJECT STAGE 2 SPRAY FOAM SECTOR ENVIRONMENTAL MANAGEMENT FRAMEWORK THAILAND HCFC PHASE-OUT PROJECT STAGE 2 SPRAY FOAM SECTOR Made by Department of Industrial Works, Ministry of Industry Consultants Assist. Prof. Dr. Amarin Kongtawelert Department of Occupational Health and Safety Faculty of Public Health Mahidol University Year 2019 Page 103 Edition 1 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works CONTENTS Page List of Abbreviations ii 1. Introduction 1 2. Objectives of the environmental management framework 2 3. Project description 3 4. National Laws and Regulations 7 5. World Bank Safeguards Policies 15 6. Environmental impact and other effects 17 7. Mitigation measures and Environmental Management Plan (EMP) 19 8. Conditions and procedures for preparing an environmental management plan (EMP) 21 9. Monitoring and Reporting 22 10. Roles and responsibilities for implementation of Environmental Management Framework 23 11. Training and capacity building for EMF Implementation 25 12. Technical assistance for participating spray foam enterprises 26 13. Grievance Redress Mechanisms (GRM) 27 14. Budget for EMF/EMP implementation 28 15. Stakeholders Consultations 29 ANNEX ANNEX A Schematic diagram of a spray foam unit and Chemical formula 31 ANNEX B Safety Data Sheet 32 ANNEX C Personal Protective Equipment for spraying foam 83 ANNEX D Chemical management 84 ANNEX E Environmental Management Plan (EMP) 85 - Attachment 01 88 - Attachment 02 89 - Attachment 03 92 - Attachment 04 94 - Attachment 05 95 - Attachment 06 96 - Attachment 07 97 - Attachment 08 98 ANNEX F Minutes of meeting, listening and commenting 99 References 103 i Environment Management Framework (EMF) Spray Foam Sector Department of industrial works List of Abbreviations CAS No. Chemical Abstracts Service Number CFC Chlorofluorocarbon CO2 Carbon dioxide DIW Department of Industrial Works EMF Environmental Management Framework EMP Environmental Management Plan GHG Greenhouse Gas GHS Global Harmonized System GSB Government Savings Bank GWP Global Warming Potential HCFC Hydrochlorofluorocarbon HFO Hydrofluoroolefin HPMP HCFC Phase-out Management Plan MLF Multilateral Fund SDS Safety Data Sheet MT Metric Ton ODP Ozone Depletion Potential ODS Ozone Depleting Substances PU Polyurethane ii Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 1. Introduction Thailand ratified both the Vienna Convention on Protection of the Ozone Layer and the Montreal Protocol (MP) on Substances that Deplete the Ozone Layer on July 7,1989. As an Article 5 signatory of the MP, Thailand has fulfilled its obligations to phase out consumption of all controlled substances except for HCFCs. The Department of Industrial Works has revised the guidelines of import HCFCs into the country in accordance with the Montreal Protocol's obligations and conditions for receiving multilateral funds under the Montreal Protocol. All According to the Notification of Department of Industrial Works on Guideline of the HCFC import for domestic usage, B.E. 2559 (Issue 2)). The implementation of the Stage I HCFC Phase-out Project had completed in December 2018. The proposed Thailand HCFC Stage II project is a continuation of Thailand HCFC Phase-out Stage I Project targeting reductions of HCFC-141b in the spray foam sector. The project will provide technical and financial assistance to eligible manufacturers, primarily in the spray foam sector, to reformulate new foam systems (polyol and blowing agent) and retooling manufacturers with new equipment compatible with new foam systems. The proposed project will support adoption of low-GWP blowing agents consistent with the Kigali Amendment of the MP. The proposed alternatives for conversion from HCFC 141b in spray foam sector are HFOs and CO2 and it is likely that two HFOs (HCFO-1233zd and HFO-1336mzz-Z) will be selected as alternatives for the conversions. In addition, the project will support a limited number of eligible commercial refrigeration manufacturers to demonstrate low-GWP alternative technologies for commercial refrigeration equipment. The project will be implemented with the World Bank as Implementing Agency and in accordance with the World Bank Policies and Guidelines and the guidelines of the Montreal Protocol. As per the Bank Guidelines, Environmental Management Plans (EMP) will have to be prepared for each participating Spray foam enterprise before they sign Sub-grant agreements for their HCFC-141b phase-out. Since foam companies to be funded cannot be identified prior to the project appraisal, Mahidol University has been engaged by the DIW to assist in preparation of this Environmental Management Framework (EMF) which aims to provide guidance for each participating foam enterprise on preparation of EMP. The EMP will be prepared by each spray foam enterprise and attached with sub-grant proposal during the HCFC-Stage II implementation phase before signing of sub-grant agreement. Each of the spray foam enterprise will also comply with relevant requirements stipulated in Thailand laws and regulations including on occupational health and safety, environment and social. 1 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 2. Objectives of the Environmental Management Framework (EMF) This EMF has been prepared in consistent with the World Bank’s Operational Policy (OP)/Bank Procedure (BP) 4.01 - Environmental Assessment (EA) and in accordance with Thai National Laws and Regulations. To the extent relevant the applicable World Bank Group Environmental Health and Safety Guidelines has been considered when preparing the EMF. The main objectives of the EMF are to: (1) Identify potential risk associated with the conversion to alternative spray foam system; (2) Provide information on safety and environmental requirements and capacities needed for the introduction of alternative spray foam system; (3) Describe procedures and methodologies for proper storage and handling of alternative spray foam blowing agent, in particular protective equipment and safety measures for the conversion to alternatives spray foam system in compliance with applicable national regulations and international standards. (4) Provide guidance for the preparation of an Environmental Management Plan (EMP) for participating spray foam enterprises; 2 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 3. Project description 3.1 Thailand HCFC Phase-Out Stage II Project The project development objective is to contribute to reducing HCFC consumption in Thailand. The project consists of four proposed components as described below. Component 1: Investment in HCFC Consumption Reductions The project will finance conversion in the spray foam sub-sector and for demonstrating alternative low-GWP non-ODS technology in the commercial refrigeration sector. This includes: (a) Provision of sub-grants to beneficiary enterprises in the spray foam sub-sector to carry out HCFC consumption reduction subprojects; (b) Demonstration sub-project for the conversion of high GWP HFCs used as refrigerants for manufacturing commercial refrigeration equipment. Financial support will be provided to spray foam enterprises consuming HCFC-141b in their production processes (i.e., as a blowing agent). This covers about 71 enterprises and system houses. The project will finance conversion to low-GWP HFO alternatives i.e. HFOs and CO2 and it is likely that two HFOs (HCFO-1233zd and HFO-1336mzz-Z) will be selected as alternatives for the conversions. The following cost will be supported by the project: (i) handling and storage for HFOs and new foam systems; (ii) trial production and training of spray foam enterprises; and (iii) incremental operating cost of the alternative technologies for a transitional period. For system houses, the project will finance: (i) development and testing of new foam formulation based on HFOs; (ii) cold room for storage of HFOs: and (iii) premixing unit for HFOs and polyols. In addition, the project will finance a demonstration sub-project for the conversion of high GWP HFCs used as refrigerants for a commercial refrigeration manufacturer (Patana Intercool). Component 2: Technical Assistance This component is designed to strengthen capacities of relevant government agencies, technical institutes and private entities that engage in HCFC import/export, handling, use, and end-of-use including policy and standard development to facilitate market transformation in the spray foam sector. Component 3: Project Management This component will provide technical assistance support to the project management units (PMUs) of DIW and GSB, which will continue to provide project management support on a day-to-day basis (building on experiences from Stage I). Component 4: Strengthening of the National Ozone Unit (NOU) This component will provide technical assistance to strengthen the capacity of the NOU to fulfill the obligations of the Recipient under the Montreal Protocol. 3 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 3.2 Current blowing agents application Polyurethane Foam is a product from polymerization reaction between isocyanate and polyol. Thermal insulation of the polyurethane foam can be obtained from tiny cavities in its structure. The small cavities resulted from the tiny gas generated impromptu with the polyurethane polymer. The gas can be carbon dioxide derived from the reaction between isocyanate and water (water-blown technology), and the addition of volatile organic compounds in the polymerization reaction (called blowing agents). The heat from exothermic reaction turns volatile liquid to gas within polyurethane foam. For foam spraying, the two reactants containing in two separate 200-L drums are mixed altogether. The first drum is isocyanate (MDI) and the latter is a mixture of polyol, water and a blowing agent. The currently used blowing agent is HCFC-141b will be replaced with a mixture of water and HFO-1233zd or a mixture of water and HFO-1336mzz-Z. The two chemical drums are pre-heated and delivered with a pump. They are mixed at the spraying gun to form polyurethane foam. The schematic diagram of polyurethane foam spraying unit is shown in Annex A. 3.3 Background of PU Spray Foam Sector in Thailand Montreal protocol gains the most accomplishment in conservation of the world environment. The protocol set the goal to decrease and eliminate the use of ozone depleting substances. Hydrochlorofluorocarbons (HCFCs) have been temporarily substituted for Chlorofluorocarbons (CFCs), which were widely used and banned on January 1, 2010 under the Montreal protocol. HCFCs still have an impact on depleting the ozone layer but their ozone depletion potentials are less than those of CFCs. Moreover, HCFCs are also Greenhouse Gas (GHG) which have Global Warming Potentials (GWP) in a range of 100 to 1,000 compared to carbon dioxide whose GWP is 1. The alternative substances in spray foam sector such as HFOs have zero ozone depletion potential (ODP) and low GWP. Table 3-1 Ozone depletion potentials and Global Warming Potentials for several blowing agents Chemical name Flash point (°C) ODP GWP CFC-11 No data 1 4750 HCFC-141b No data 0.11 725 HFC-134a No data 0 1300 HFC-245fa No data 0 1050 HFC-365mfc - 24 0 840 n-Pentane - 49 0 11 Iso-Pentane - 51 0 11 Cyclopentane - 37 0 11 CO2 No data 0 1 HFO 1233zd Not flammable 0 1 HFO 1336mzz-Z Not flammable 0 2 4 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works According to department of industrial works, HCFC Phase-Out Management Plan (HPMP) Stage I has been addressed in PU foam sector since 2016 except for spray foam sector. Based on the results from the survey conducted for Thailand HCFC Stage II project, the spray foam sub-sector consists of 102 enterprises which currently 71 enterprises are eligible for Thailand HCFC Stage II support. These spray foam enterprises can be divided into three groups according to their annual HCFC 141b consumption rate: Group 1: More than 10 MT/Year (5 enterprises); Group 2: Between 2-10 MT/Year (8 enterprises); Group 3: Less than 2 MT/Year (58 enterprises) 3.4 Field visit 3.4.1 Storage area The study team had surveyed at the chemical storage areas of the selected enterprises, interviewed the owners for the purchasing, storage procedure before using the chemicals in the fields. The enterprises visited comprised of 1 of Group 1 enterprise, 2 of Group 2 enterprises, and 1 of Group 3 enterprise. 3.4.2 Working areas of spray foam The study team had surveyed the spraying foam areas and interviewed the owners for the standard procedures; chemical transportation, installation of the spraying equipment, spraying gun, spraying process, personal protective equipment (PPE), cleaning of the equipment after used, chemical exposure from foam spraying. The survey included visits to Group 1 enterprise (1 enterprise) and Group 2 enterprise (1 enterprise). According to the survey, we found that the work procedures of Group 1 and Group 2 enterprises are similar except for the use of personal protective equipment. Group 1 ( large enterprise) has paid more attention to health and safety of the workers than Group 2 ( medium enterprise) due to the fact that the workers from large enterprises have been trained for safety before they get to work in factories. It is a basic requirement for the outsourcing before they are allowed to work. In terms of chemical storage, the enterprises usually order the chemicals in quantity required for each work from suppliers. They do not store chemicals in a large quantity. 3.5 Chemical substitute 3.5.1 A mixture between hydrofluoroolefins (HFOs) and water (H2O) Hydrofluoroolefins or HFO are a group of unsaturated hydrofluorocarbon potentially used as blowing agents. The compounds in this class, which will be substituted for HCFC-141b, include HFO-1 2 3 3 zd and HFO-1 3 3 6 mzz-Z. They both have considerably low GWP and zero ozone depletion potential (ODP). The main reason of lower values results from their shorter life cycle of the molecules in the atmosphere. They also have low toxicity and better energy efficiency. This type of blowing agents is pre-blended a tank with polyol by a supplier. For HFO-1 2 3 3 zd, it has quite low boiling point (1 9 oC) compared to Thailand ambient temperature. It is supplied in a compressed gas cylinder. A cylinder should be kept in well 5 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ventilated area that is protected from sunlight and should not expose to temperature exceeding 5 5 oC. Read guidelines for storage, handling or SDS before use the chemicals. Before off-loading the product, it is suggested to store the container indoor overnight, if possible. Carbon dioxide is a product from the reaction between isocyanate and water. This gas is simultaneously generated with the polymerization reaction and provides the cavity in polyurethane foam. In particular, CO2 is environmentally friendly and offers a long-term sustainable solution, due to its zero Ozone Depletion Potential (ODP) and its lowest Global Warming Potential (GWP), set equal to 1 as reference to other greenhouse gases. Also, carbon dioxide is non-flammable and non-toxic. The additional information of substitutes are listed in Annex B. 3.6 Cleaning solution for spraying equipment and apparatus Methylene chloride Methylene chloride is an organic solvent that is recently used to clean spraying equipment and all apparatus. Methylene chloride is clear liquid, nonpolar, water immiscible. The density is 1.32 g/mL with the boiling point 39.6oC, which make methylene chloride easily evaporates at the ambient temperature. In terms of toxicity, methylene chloride causes skin and eye irritant. Moreover, it is probably carcinogenic to humans. Therefore, the worker must handle methylene chloride with care. The chemical should not get exposed to skin or inhalation. The additional information of methylene chloride and PPE are listed in Annex B and C. 6 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 4. National Laws and Regulations To prevent and control the impact, if any, from implementation of the HCFC Phase-Out Stage II, the participating spray foam enterprises shall comply with national laws and regulations related to health and safety and environment listed below. These laws are enforced by Ministries of Industry, Labour Welfare and Protection, Public Health, and Interior Affairs. Table 4.1 Relevant National Laws and Regulations Laws and Regulations Brief Description of Laws / Regulations Ministry of industry Factory Act B.E. 2535 (1992) Factory Act (2nd Issue), B.E. 2562 (2019) was announced in and Factory Act (2nd Issue) the Government Gazette on April 30th of 2019 and shall become B.E. 2562 (2019) enforceable in the next 180 days upon the publication. The definition of “Factory” means a building, place, or vehicle with a machine of 50 or more horse powers or an equivalent power, or has 50 or more workers with or without any machine for factory engagement according to category or type of factory as prescribed in a ministerial rule. Factory Act, B.E. 2535 (1992) categorized factory into 3 groups which are Group 1, Group 2 and Group 3 as according to the Annex in the Ministerial Regulation (Issue 1) which described each group as followed: (1) Group 1 factory is factory of the type, kind, and size that can be established and engaged immediately upon the desire of a person for factory engagement. (2) Group 2 factory is factory of the type, kind, and size that a person must notify the authority for factory engagement and abide by the Ministerial Regulation (Issue 2). (3) Group 3 factory is factory of the type, kind, and size that a person must be granted a factory establishing permit prior to the factory engagement and abide by the Ministerial Regulation (Issue 5). Factory Act (2nd Issue), B.E. 2562 (2019) prescribed Group 1 and 2 factories located in local government organization area will be controlled by their own local government organization and regulated by Ministry of Industry. 7 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations Hazardous Substance Act B.E. HFO-1336-mzz-Z is listed as Category 3 Hazardous Substance: 2535 the production, importation, exportation, or possession of which requires licensing obtained from Ministry of Industry and must comply to all the regulations, also, responsible to the damage or loss caused by this hazardous substance. The producer of hazardous substance shall have the duty of care in procuring substance to be sued as production material, laying down trustworthy production method and procedure, providing safe, strong, and secure container for use, moving and transportation, providing labels that clearly and sufficiently display the harmful nature of such substance, providing storage propriety and examining the propriety of the recipient or the person who could be expected to be the recipient of such hazardous substance from him or her. Industry Ministerial The employer of Group 2 and 3 factories must have the Regulation on Prescribing electrical system installation as-built drawing and lists of the Standard for Factory inventories with the drawing. This drawing must be prepared by Electrical Safety System B.E. certified professional electrical engineer. All components of the 2550 (2007) electrical system must comply with international or universal standard. Annual inspection of the electrical system is required and must prepared by certified professional electrical engineer. An inspection report and related documents must be kept at the workplace in case the ministerial inspector requested. Industry Ministerial Factory building must have full coverage of fire detector Notification on Fire and fire alarm equipment as appropriate to each area and Prevention and Protection emergency exit. Particularly the non-occupied area where B.E. 2552 (2009) electrical equipment is installed or used or storage area of flammable or combustible materials, automatic fire detection and fire alarm systems must be installed. Fire alarm equipment must be of self-trigger type independent from the power system for lighting or machinery, or equipped with electrical backup system for at least 2 hours. Factory building must Install the portable fire extinguishers throughout the area and perform the regular check-up, schedule maintenance according to the procedure. Must install the grounding or bonding to any equipment, devices, storage tanks, reactors which use the flammable material. 8 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations Must set up the fire prevention, protection and evacuation planning according to Fire Prevention and Protection for Factory Handbook B.E. 2552 (2009) Industry Ministerial An employer must perform the annual inspection, analysis, Notification on Safety and working conditions related to heat, lighting, and noise level Standard of Working at least once a year. Methods for inspection and analysis must Environmental Conditions in perform according to the universal standard. The report must Workplace B.E. 2546 (2003) be prepared by certified person and keep at workplace in case of requesting by ministerial officers. For occupational heat exposure level in workplace, it must not exceed the allowable average WBGT based on level of working intensity. There are 3 level of working intensity which are light, medium, and heavy level. If the temperature of working environment exceed the allowable limit, the employer must notify the employee and try to resolve this issue immediately. If the problem still exists, personal protective equipment for protecting heat exposure must be provided to employees and training must be provided. For recommended lighting level at work, every workplace must have suitable and sufficient lighting based on the workplace area and characteristics of tasks. Preventing glare or flicker from lighting must be performed for equipment usage. For noise level control in workplace, the levels of exposure to noise of your employees average over a working day or week should not exceed the recommended level based on number of working hours. If the noise level exceeds the limit, the employer must notify the employee and try to resolve this issue immediately. Industry Ministerial HFO-1336-mzz-Z was added into 5. 1 th inventory list under Notification on Hazardous the responsibility of the Department of Industrial Works. Substances Inventory (3 rd Issue) B.E. 2559 (2016) 9 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations Industry Ministerial Hazardous substance operators shall carry out safety Notification on Storage of measures in accordance with the notification of the Department Hazardous Substances under of Industrial Works regarding the storage manual, chemicals, and the Responsibility of the hazardous substances B.E. 2550 (2007) Department of Industrial Works B.E. 2551 (2008) Industry Ministerial Duties of safety transportation of hazardous substances for Notification on the producer, importer, exporter, person having in possession Transportation of Hazardous of the hazardous substances, transporter, and recipient of Substances under the hazardous substances were shown in this Government Responsibility of the notification. Department of Industrial Works B.E. 2558 (2015) Industry Ministerial The allowable time limit for storing waste or unwanted Notification on Disposal of materials is not more than 90 days. If the factory required to Waste and Unwanted store more than 90 days, it must obtain a permit (SK.1) from the Materials B.E. 2548 (2005) Department of Industrial Works. The factory must have emergency response incident plan such chemical leakage, fire or explosion of its own waste or unwanted materials as shown in Annex 3 in this Government notification. In order to transport waste or unwanted materials out of the area, it required the permission from the director-general of Department of Industrial Works. In case of hazardous waste, the factory must use the authorized personnel or company which registered with the Department of Industrial Works for collecting, transporting, or treating/disposing of their hazardous waste. The manifest of waste must be keep at the generator (factory), transporter, and send to Department of Industrial Works. Annual report (SK3) must be submitted to Department of Industrial Works within March 1st, of the following year. Industry Ministerial This Government Notification is about the storage of Notification on Storage of chemicals and hazardous substances handbook which Chemicals and Hazardous published in B.E. 2550 (2007) by Department of Industrial Works, Substances Handbook B.E. Ministry of Industry. 2550 (2007) 10 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations Ministry of Labour Occupational Safety, Health, An employer shall provide an occupational safety, and Working Environment health and environment training to be attended by an Act B.E. 2554 (2011) Executive, a Supervisor and an employee in order to safely administer, manage and operate the occupational safety, health and environment. Whereas an employer employs an employee to work, changes work, changes workplace or changes machinery or equipment that may be harmful to life, physique, mentality and health of an employee, an employer shall provide a training for every employee before commencing work. The training shall be in conformity with criteria, methods or terms as stipulated by the Director-General. Labour Protection Act B.E. An employer shall treat male and female employee 2541 (1998) equally in employment unless description or nature of work prevents such treatment. An employer shall concern with human right, fairness, safety and health of the employee: male, female, pregnant, and young workers (under 18 years of age), working hour, vacation days, wages, overtime pay, severance pay, legal right, welfare and employee welfare fund. Labour Ministerial Regulation An employer shall provide the fire prevention and Prescribing the Standard for protection system and maintain this system to the efficiently Administration and and safely operation condition. Procedures for extinguishing fire Management of and emergency evacuation shall post in workplace. Occupational Safety, Health A workplace with more than 10 employees shall conduct and Working Environment on the fire prevention and protection plan and provide at least 2 Fire Prevention and emergency route to exit from the building with appropriate Protection B.E. 2555 (2012) lighting combined with backup power unit on each floor. An evacuation route shall be able to lead employee safely exit the building within 5 minutes. A workplace with more than 2 storeys or has more than 300 square meter shall install fire detector in every floor and have portable fire extinguisher based on type of fire. Each floor shall provide a map with the portable fire extinguisher location. Any obstruction objects shall not place in the area where a fire portable extinguisher locates. 11 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations An inspection of fire portable extinguisher shall perform at least once in every 6 months with validate date of inspection date. A fire drill shall conduct at least once a year with at least 40 percent of the employee who work in workplace Labour Ministerial Regulation An employer shall provide working procedure regarding the Prescribing the Standard for operation of safety, occupational health, and working Administration and environment regarding electricity for employees to follow. Management of An employer shall provide training for employees Occupational Safety, Health performing electrical work to have knowledge, understanding and Working Environment on and skills necessary to work safely according to the assigned Electricity B.E. 2558 (2015) duties. An employer shall provide and maintain the electrical circuit diagram installed in the establishment. An employer shall inform employee to the hazard of electricity by electrical safety poster. An employer shall perform the maintenance all electrical system in safely condition. An employer shall install appropriate numbers of electrical outlets, equipment, and surge protectors though out the workplace with universal standard certified by Engineering Institute of Thailand. Labour Ministerial Regulation An employer shall make a signboard with the text inscribing Prescribing the Standard for “Confined space, Danger, Do not Enter” The signboard shall be Administration and in conspicuous size and installed openly at the entrance and Management of exit of every confined space. Occupational Safety, Health An employer shall not permit employee or any person to and Working Environment on enter the confined space unless the employer has provided the Confined Space B.E. 2562 safety measure in according to this Ministerial Regulation; and (2019) such employee or such person has been permitted by the person who is responsible for granting permission and who is trained. 12 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations An employer shall provide the health checkup to employee who work with risk within 30 days from the first day of employee is employed and the subsequent health checkup shall be conducted at least once a year. A health checkup shall be conduct to the employee when there are new risk factors take place or when changing to the difference of tasks/jobs. A detail of health checkup shall record in employee health report. An employer shall inform the result of health checkup to the employee. In case the healh checkup result is normal, such employee shall be informed within seven days from the date of acknowledgement of the result. If there is an abnormal result, an employer shall inform employee within 3 days and required the medical treatment to that person. An employer shall investigate the abnormality of the result in order to prevent this type of incident to repeat in the future and required to submit the result of the investigation to the labour inspector within the 30 days from the abnormality has been found. Any employees who could not perform the same duty which result by the abnormality, an employer shall proceed to change such job. Department of Labour Portable fire extinguisher standards shall comply with Protection and Welfare National Fire Protection Association (NFPA), American National Notification on Portable Fire Standards Institute (ANSI), Australia Standard (AS), British Distinguisher Standard B.E. Standard (BS), or International Standardization and Organization 2556 (2013) (ISO) Department of Labour Personal protective equipment shall comply with Protection and Welfare International Standardization and Organization (ISO), European Notification on Personal Standards (EN) Australia Standards/New Zealand Standards Protective Equipment (AS/NZS) American National Standards Institute (ANSI), Japanese Standard B.E. 2554 (2011) Industrial Standards (JIS), The National Institute for Occupational Safety and Health (NIOSH), Occupational Safety and Health Administration (OSHA) or suitable to their nature of works. 13 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Table 4.1 Relevant National Laws and Regulations (cont.) Laws and Regulations Brief Description of Laws / Regulations The Ministry of Interior Building Control Act B.E. 2522 Buildings under control of use under this Act are any (1979) building occupied as warehouse, hotel, commercial, medical center, industrial, education institute, public health or others shall acquire a permit or notify to the local officer when there are construction, modification, or transportation in order to protect the safety in life, properties and health of people who occupied in these types of buildings and protect the environmental pollution. 14 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 5. World Bank Safeguards Policies The World Bank applies 10 Safeguards Policies, which set the mandatory requirements for Borrowers relating to the identification and assessment of environmental and social impacts. Thailand HCFC Phase-Out Stage II project triggers one safeguards policy namely Environmental Assessment OP/BP 4.01. This EMF has been prepared to assess and address potential impacts from conversion of spray foam from HCFC 141b to low-GWP alternatives using HFOs and/ CO2 according to OP/BP 4.01 requirements. To the extent relevant the World Bank Group EHS (Environment Health and Safety) Guidelines have been considered in the preparation of the EMF. The relevant content of World Bank OP 4.01 and EHS is described in Table 6.1 below: Table 5.1 World Bank Safeguards World Bank Abstract/Descriptions Safeguards Environmental Environmental Assessment is used in the World Bank to identify, avoid, Assessment (EA) (OP and mitigate the potential negative environmental impacts associated 4.01)4 with Bank operations. EA is a process whose breadth, depth, and type of analysis depend on the nature, scale, and potential environmental impact of the proposed project. EA evaluates a project’s potential environmental risks and impacts and identifies ways of preventing, minimizing, mitigating, or compensating for adverse environmental impacts and enhancing positive impacts. This project triggers OP 4.01 because its supports for conversion from HCFC-141b to Low-GWP technology in Spray Foam sub-sector and for one demonstration project to convert commercial refrigeration to R- 32 technology or HFC/HFO blended technology may generate low to moderate risks to the environment and occupational health and safety. The anticipated impacts will be site-specific and can be mitigated by proper mitigation measures. Therefore, the project is classified as Category B EA according to the World Bank OP/BP 4.01. This EMF has been prepared to assess and address potential impacts from conversion of spray foam from HCFC 141b to low-GWP alternatives using HFOs and/ CO2 according to OP/BP 4.01 requirements. 15 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works World Bank Group The Environmental Health and Safety Guidelines (EHS) are technical Environmental, Health reference documents with general and industry-specific examples of & Safety (EHS) Good Industry Practice (GIP), as defined in IFC’s Performance Standard Guidelines5 on Pollution Prevention and Abatement. The EHS Guidelines contain the performance levels and measures that are normally acceptable to the World Bank Group and generally considered to be achievable in new facilities at reasonable costs by existing technology. When host country regulations differ from the levels and measures presented in the EHS Guidelines, projects are expected to achieve whichever is more stringent. 16 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 6. Environmental impact and other effects Thailand HCFC Phase-Out Stage II project aims to contribute to reducing HCFC consumption in Thailand by replace HCFCs with low-GWP alternatives. The project will provide technical and financial assistance to eligible manufacturers, primarily in the spray foam sector, to reformulate new foam systems (polyol and blowing agent) and retooling manufacturers with new equipment compatible with new foam systems which the proposed alternatives are HFOs (HFO- 1233zd and HFO-1336mzz-Z) and CO2. While conversion from HCFCs provide benefits to the global environment as HCFCs are ozone depleting substances and high global warming gases, conversion to alternatives substances could lead to other adverse impacts which should be assessed and mitigated properly. The following section describe positive and negative environmental and social impacts from the proposed conversions. Additional details on chemicals properties, effect and guidance for proper handling are available in Chemical Safety Data Sheet (SDS) (Annex B). 1) Ozone Depletion: Phasing-out of HCFC 141b by the project will contribute positively to the recovery of the ozone layer due to its will support conversion from HCFC 141b which is an ozone depleting substance to HFOs (HFO-1233zd and HFO-1336mzz-Z) and/ CO2 alternative which are non-ODS. 2) Global Climate Change: HCFC 141b is greenhouse gas with global warming potentials (GWP) of 725. The project will have a positive impact on the global climate change as alternative blowing agents are low-GWP substances with approximately 362- 725 times lower GWP than that of HCFC 141b. 3) Local Air Pollution: HCFC, HFOs and CO2 are chemically stable and do not affect local air quality. While the environmental impact of this emission is expected to be minor, emissions from the foam blowing process will be contained through regular leak inspections. 4) Soil and water contamination: other chemicals used in spray foam industry are Methylene Diphenyl Diisocyanate (MDI), amine catalyst and fire retardants. The probability that a spill of polymeric MDI (liquid at room temperature) contaminates the soil and water is very low, because the floor of the foam storage areas and foam spraying areas are typically cement coated with an anti-leakage, low permeability chemical layer such as epoxy. If MDI leaks into the soil, it will react with moisture or water, and the reaction would result in CO2 and insoluble polyurea compounds, which are non-biodegradable and chemically inert. Fire retardant and amine catalysts (very small amount) are mixed with polyol by system house suppliers. They remain in the final foam products and are not emitted to the environment during foam spraying or later. 5) Fire hazards: HFOs and CO2 are not flammable, so there is no impact on fire hazard from the use of foam spraying. 6) Occupational health and safety: The project will support participating spray foam enterprises to convert from HCFC 141b to lower GWP (HFOs /CO2) technology. The 17 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works conversion will involve replacement of foam blowing agent, HCFC 141b, with the new alternatives (HFO-1233zd and HFO-1336mzz-Z). Other chemicals used for the foam production comprising of polyol and isocyanate are still the same (with some adjustment in formulation). Both HFO-1233zd and HFO-1336mzz-Z are nonflammable substances. HFO-1233zd is considered practically nontoxic by the inhalation route of the exposure. Workplace exposures with HFO- 1336mzz-Z would likely occur via the inhalation route. The 4-hour LC50 in rats of >102,900 ppm (v/v) indicates that the substance has low acute inhalation toxicity. However, Personal Protective Equipment (PPE) should be worn to prevent possible exposure to the chemicals used for the foam spraying works. Other OHS risks associated with foam spraying may be derived from different working conditions at foam application sites for example working at height, working in areas with poor ventilation, working in attics and crawlspaces, working in high temperature or outdoor areas, etc. These risks can be prevented/minimized through implementation of good practices and use of PPE as described in Chapter 7. In addition – and unrelated to the conversion technology supported by the project – participating enterprises must implement and observe certain OHS measures related to the use of Isocyanate (MDI), which is one of the chemicals used in foam production and which is a moderate health and environmental hazard. 7) Waste management: solid wastes generated from foam spraying works include scrap spray PU foam, liquid spray PU foam component chemicals and empty drums. These solid wastes are expected to be minimal and should be disposed of in compliance with laws and regulations on waste disposal and in accordance with guideline in the manufacturer’s SDS. 8) Social impact: The project support to participating enterprises will be carried out within the existing locations of project beneficiaries or in spray foam application sites. There will be no land acquisition or involuntary resettlement and job lost related impact from the project activities. Similar to the outcome of the project in Phase I, the outcome of the phaseout in this project is gender neutral. The project will provide equal opportunity for male and female workers to participate in training and other capacity building activities. In addition to above discussion, all of the potential participating spray foam enterprises are Small-Medium enterprises, number are limited (around 71 enterprises) and most of them are in Group 3 which has HCFC 141b consumption less than 2 MT/Year and can be considered as small/micro-scale investment. Considering that the project will finance conversion of HCFC 141b blowing agent to Non-ODS and low-GWP chemicals that are non-flammable and has low toxicity and that potential participating enterprises are only 71 small-medium enterprises, it could be concluded that the anticipated adverse impacts on the environment and social from the project are low to moderate and could be managed through implementation of good mitigation measures. 18 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 7. Mitigation measures and Environmental Management Plan (EMP) 7.1 The necessity of an environmental management plan Participating spray foam enterprises shall prepare Environmental Management Plan (EMP) following forms provided in Annex E, which covers mitigation measures described in the following section. The enterprises are required to follow mandatory requirements in regulations related to environmental, social and OHS management applicable to their operations. 1. Hazard Awareness The enterprises should ensure that their employee receive adequate trainings to build awareness, knowledge and skill for a safe working condition. The trainings topics may include safe work practices, equipment inspection and maintenance, storage of hazardous materials in accordance with the announcement of the Department of Industrial Works on the Manual for Storage of Hazardous Substances 2007, working at height, proper working posture, working outdoors/ in hot weather, use and maintenance of personal protective equipment, etc. Inspection check list should also be provided and implement before work commencement. 2. Personal protective equipment PPEs shall be provided and strictly enforced. For staff working in the foam spraying area PPEs may include protective cloth, respiratory protection systems/masks, chemical goggles, and chemical protection gloves, particularly when deal with spilled chemicals, safety harness (in case working at height), etc. (Annex C) 3. Waste management Storage and disposal of wastes including scrap spray PU foam, liquid spray PU foam component chemicals and empty drums must comply with the requirements specified in the Manual for the Storage of Hazardous Substances, 2007 announced by the Department of Industrial Works, guideline in the manufacturer’s SDS and follow engineering best practices as practical. 4. Installation of electrical systems and equipment Comply with the standards in Thailand in determining the standard of electrical equipment installation in industrial plants, such as the Industrial Ministerial Regulation prescribing safety standards regarding electrical systems in factories, 2007 and other relevant regulations. Inspect to ensure that electrical equipment and wiring are in safe and good conditions before carrying out foam spraying works. 5. Ventilation In the case that it is necessary to carry out works in poor ventilated areas e.g. ???, efforts should be made to improve ventilation and air circulation of working areas. For example, install suction fan, provide temporary air opening, where possible. 6. Fire prevention and suppression In the chemical storage area should comply with the laws and regulations on fire prevention and suppression systems, such as the installation of movable fire extinguishers, etc. and follow the manual for the storage of hazardous chemicals. 19 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 7. Standards of operation and training regulations Participating enterprises should establish work procedures and ensure that employee who involve in receiving, storage, lifting, moving, and spraying foam has adequate training to perform works safely. 8. Inspection and maintenance Safety inspections and assessments before and after the use of machines and equipment in the foam injection process should be carried out as specified in Annex E. In addition, spray foam enterprises can also seek advice from equipment supplier. 9. Working at Height In case foam spraying works involve working at height activities, sufficient plan, training and measures should be provided. This include provision of secure scaffolding/guard rails, sufficient and proper PPEs (e.g. safety harness) and training on how to use PPEs, only allow people with sufficient skills and experience to perform the task, etc. 10. Working in confined spaces (if relevant)/ Attics Working in confined spaces such as the space under the roof, under the floor of a building that is tall enough to crawl (Crawlspaces), and silos. Employers must have a safety plan and measures for employees who work in such conditions including install ventilation equipment, provide mask/breathing apparatus, and oxygen measuring instruments, and other necessary PPEs to prevent injury or incident at work place. The enterprises must follow regulatory requirements concerning working in confined spaces that are applicable to their works. 11. Working in hot weather In case of spraying foam in hot areas such as on the roof or under the roof especially in the summer, employers must provide protection from hot air hazards, such as proper work clothes, providing adequate clean drinking water, and periodic breaks. 12. Transporting chemicals to the work site Vehicles that transport chemicals from the company to the work site must consider requirements on safety of chemical transportation where relevant, such as vehicles must be able to prevent the leakage of chemicals into the environment and there are signs or markings showing the loading of hazardous materials attached to the vehicle clearly. 13. Chemical storage Proper storage is needed for all chemicals. Dry and cool area is needed for isocyanate because isocyanate can react with moisture or water to product carbon dioxide resulting in high pressure in a drum. All the SDS are available and accessible. (Annex D) 20 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 8. Conditions and procedures for preparing an environmental management plan (EMP) For the spray foam company that wants to participate in this project will be a company listed in the spray foam company list of the Department of Industrial Works by the steps in preparing the environmental management plan (EMP) of each company Can study from the EMP preparation guidelines in the Annex E Participating enterprises must prepare an environmental management plan (EMP) following procedures and forms provided in Annex E, which the enterprises can seek advice from the DIW-Project Management Unit (PMU) in preparing the EMP. The enterprises shall submit EMP together with technical proposal to the Government Savings Bank (GSB) and copy to PMU in order to request for financial support to convert to new foam system. The PMU will evaluate the enterprise eligibility for project support based on their established date and compliance with the multilateral fund (MLF) criteria. Once eligibility is confirmed, GSB and PMU will review the subproject proposals and supporting documents, verify HCFC consumption, appraise and confirm the technical and financial feasibility of the proposals and recommend the appropriate level of funding. 21 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 9. Monitoring and Reporting The DIW-PMU will take overall responsibility to ensure that the EMF requirements are effectively implemented including carrying out supervision and monitoring of EMP implementation by participating enterprises. Each participating enterprise will be required to submit EMP monitoring form to the PMU and GSB within 6 months from sub-grant agreement signing using forms in Annex E. The PMU will randomly conduct site visits to monitor the safeguard implementation compliance periodically, prepare biannually project safeguards progress report that provide an overview of project safeguards implementation status and performance and share with the World Bank in each Project Implementation Support Mission (ISM). The World Bank task team will supervise the implementation of the project including its environmental and safety provisions during the project ISM. Supervision will include discussion with selected spray foam enterprises and site visits. 22 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 10. Roles and responsibilities for implementation of Environmental Management Framework 10.1 Spray Foam enterprises 10.1.1 Before conversion: • Prepare an EMP for the implementation of the conversion project. • Ensure that valid operating or business license is in place. • Request from chemical supplier the safety data sheets for each chemical used in the foam production process. 10.1.2 After start of production: • Implement measures as specified in the EMP. • Submit EMP monitoring form to the PMU and GSB within 6 months from sub-grant agreement signing using forms in Annex E • Report accidents to the competent authorities and PMU. • Report production and consumption data to the Project Management Unit (PMU) as required (foam produced, and HFOs consumed). 10.2 The Project Management Unit (PMU) The PMU of Department of Industrial Works is responsible for the proper management and oversight of the overall HCFC phase-out project including environmental and safety aspects of each HCFC conversion sub-project. In execution of this responsibility, under guidance from Department of Industrial Works and the World Bank, the PMU will: • Set up eligible criteria for screening of participating enterprises. • Evaluate the enterprise eligibility for project support based on their established date and compliance with the multilateral fund (MLF) criteria. • Provide technical assistance or support to participating spray foam enterprises including provide advice on a preparation of EMP. • Together with GSB review and assess the adequacy of the HCFC conversion plan including the EMP of participating enterprises. • Supervise the implementation of the HCFC conversion project and the enterprise’s compliance with the agreed environmental and safety requirements and standards. • Prepare biannually project safeguards progress report that provide overview of project safeguards implementation status and performance and share with the World Bank in each Project Implementation Support Mission (ISM). 23 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 10.3 The Government Saving Bank (GSB) • Review and assess the adequacy of the HCFC conversion plan including the EMP of participating enterprises. • Include the approved EMP in the sub-grant agreement with each participating spray foam enterprise such that the responsibilities and commitments in the EMP become contractual obligations of the participating enterprise. 24 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 11. Training and capacity building for EMF Implementation It is the responsibility of the participating foam enterprise to ensure that their employees receive adequate training to perform their works safely. The trainings should cover basic safety training and use of PPE, proper storage, handling and disposal of blowing agents and chemicals as well as health, safety and environmental requirements as indicated in the EMP forms. Part of conversion cost to be financed by the project could be used for training including these required trainings. 25 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 12. Technical Assistance for Participating Spray Foam Enterprises In addition to the project financial support to spray foam enterprises which part of the cost can be used for training, the PMU and its technical consultant will be available to provide advice to participating foam enterprises on technical aspects and EMP. The technical consultant to be hired by the PMU will be fully familiar with the HCFC conversion process, including the handling of blowing agents and other chemicals, health and fire hazards and mitigating measures. 26 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 13. Grievance Redress Mechanisms (GRM) Communities and individuals who believe that they are adversely affected by the project may submit complaints to existing DIW’s Grievance Redress Mechanism and GSB’s Grievance Redress Mechanism through various channels include walk-in, fax, phone call, hotline, website, email, etc. Furthermore, there are several other channels in which affected individual or communities can submit complaints/suggestions including GRM available at the Prime Minister Office, Pollution Control Department, Federal Thai Institute, etc. as well as the World Bank’s Grievance Redress Service (GRS) system. 27 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 14. Budget for EMF/EMP implementation Participating spray foam enterprises bear the financial responsibility for the conversion including any environmental, social health and safety mitigation activities required by the EMF/EMP. The project will make an agreed payment to participating spray foam enterprises to convert to low-GWP HFO alternatives which will cover cost for: (i) handling and storage for HFOs and new foam systems; (ii) trial production and training of spray foam enterprises; and (iii) incremental operating cost of the alternative technologies for a transitional period. The cost of hiring the technical consultant by the PMU will be borne by the HCFC Phase-out Stage II Project. 28 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 15. Stakeholders Consultations Stakeholder consultation meeting on the draft EMF was held at the DIW on June 19, 2019 with participants from relevant stakeholders including spray foam enterprises, chemicals suppliers, and other interest stakeholders (Annex F). Objectives of the meeting is to present to stakeholders on: i) the project scope and objectives, activities; ii) draft EMF and its proposed measures; and iii) discuss and hear feedbacks from stakeholders for incorporating into the final EMF where appropriate. The main suggestions are as follows: 1. Attachment 04 the work procedure should be clearly classified into each step such as equipment inspection, maintenance of equipment and personal protective equipment (PPEs), and training on safe working practice with chemicals. 2. Measures for working in poor ventilation areas should be separated into 2 scenarios including i) confined space according to regulatory requirements and ii) attics or crawlspaces. 3. For working in confined space e.g. tank or silo, enterprises need to make sure that their employees are trained on working in confined space and strictly follow the requirements for safe works. For works in attics or crawlspaces that has poor ventilation, temporary opening at a roof and other places as well as installation of suction fan to encourage air flow should be provided. Works rotation for example every 20-30 minutes should be practiced to limited employee exposure to challenging works conditions. 4. Most of foam spraying works are carried out in attics where chemical mask and safety goggles can easily clogged by spray foam. In such case, operators use plastic to cover to minimize damage to PPEs. 5. Chemical protective clothing that is currently sold in a market is from foreign countries, which is not suitable for the context of Thailand e.g. climate. Operators prefer to wear long sleeves shirt and long trouser that are suitable with local climate. 6.Request for the World Bank support on trainings and provision of necessary PPEs. 29 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX 30 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX A Schematic diagram of a spray foam unit and Chemical formula Schematic diagram of a spray foam unit Chemical formula HFO/water Preblended Polyol 31 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX B Safety Data Sheet HFO-1233zd Solstice® LBA (HFO-1233zd) 000000012786 Version 1.16 Revision Date 06/16/2014 Print Date 07/22/2015 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Solstice® LBA MSDS Number 000000012786 Product Use Description Foam blowing agent Manufacturer or supplier's details Honeywell International Inc. 101 Columbia Road Morristown, NJ 07962-1057 For more information call 800-522-8001 +1-973-455-6300 (Monday-Friday, 9:00am-5:00pm) In case of emergency call Medical: 1-800-498-5701 or +1-303-389-1414 Transportation (CHEMTREC): 1-800-424-9300 or +1-703-527-3887 (24 hours/day, 7 days/week) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form liquid, clear Color colourless Odor slight Classification of the substance or mixture Classification of the Gases under pressure, Liquefied gas substance or mixture Simple Asphyxiant GHS Label elements, including precautionary statements Symbol(s) Signal word Warning Hazard statements Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. 32 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Precautionary statements Prevention: Use personal protective equipment as required. Storage: Protect from sunlight. Store in a well-ventilated place Carcinogenicity No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Substance Chemical Name CAS-No Concentration trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >99.00 % SECTION 4. FIRST AID MEASURES Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Use oxygen as required, provided a qualified operator is present. Call a physician. Skin contact: After contact with skin, wash immediately with plenty of water. If symptoms persist, call a physician. Take off all contaminated clothing immediately. Wash contaminated clothing before reuse Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician if irritation develops or persists. Ingestion: If victim is fully conscious, give a cupful of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Call a physician immediately. Notes to physician Treatment: Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media The product is not flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Carbon dioxide (CO2) Dry chemical Foam Specific hazards during This product is not flammable at ambient temperatures and firefighting atmospheric pressure 33 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run-off from firefighting to enter drains or water courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Exposure to decomposition products may be a hazard to health. In case of fire hazardous decomposition products may be produced such as: Hydrogen fluoride Gaseous hydrogen chloride (HCl). Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Special protective In the event of fire and/or explosion do not breathe fumes equipment for firefighters Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Ventilate the area. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been tested and determined safe. Ensure that the oxygen content is >= 19.5%. Environmental precaution: Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. 34 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Prevent spreading over a wide area (e.g. by containment or oil barriers). Methods for cleaning up: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Handling Handling Handle with care. Do not use in areas without adequate ventilation. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use. Advice on protection Can form a combustible mixture with air at pressures above against fire and explosion atmospheric pressure. Keep product and empty container away from heat and sources of ignition. Storage Requirements for storage Pressurized container. Protect from sunlight and do not areas and containers expose to temperatures exceeding 55 °C. Keep containers tightly closed in a dry, cool and well- ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage. Store away from incompatible substances. 35 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective measures Ensure that eyewash stations and safety showers are close to the workstation location. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Engineering measures Use with local exhaust ventilation. Perform filling operations only at stations with exhaust ventilation facilities. Eye protection Do not wear contact lenses. Wear as appropriate: Goggles or face shield, giving complete protection to eyes Hand protection Impervious gloves Gloves must be inspected prior to use. Replace when worn. Skin and body protection Wear as appropriate: Solvent-resistant gloves Solvent-resistant apron and boots If splashes are likely to occur, wear: Protective suit Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator. For rescue and maintenance work in storage tanks use selfcontained breathing apparatus. Use NIOSH approved respiratory protection. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Ensure adequate ventilation, especially in confined areas. Remove and wash contaminated clothing before re-use. Contaminated work clothing should not be allowed out of the workplace. Keep working clothes separately. Wash hands before breaks and immediately after handling the product. 36 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Exposure Guidelines Components CAS-No. Value Control Update Basis parameters trans-1-Chloro- 102687-65-0 TWA : (800 ppm) 2013 WEEL: OARS -Workplace 3,3,3- time Environmental trifluoropropene weighted Exposure Level average (WEEL) Guides trans-1-Chloro- 102687-65-0 TWA : (800 ppm) 2013 Honeywell:Limit 3,3,3- time established by trifluoropropene weighted Honeywell average International Inc. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid, clear Color colourless Odor slight Melting point/freezing point < -90 °C Method: OECD Test Guideline 102 Boiling point/boiling range 19 °C Flash point Method: ISO 2719 Note: not applicable Flammability The product is not flammable. Method: Flammability (gases) Lower explosion limit Note: None Upper explosion limit Note: None Vapor pressure 1,516 hPa at 30 °C(86 °F) Vapor density Note: (Air = 1.0), not determined Density 1.27 g/cm3 Water solubility 1.90 g/l at 20 °C Method: OECD Test Guideline 105 Partition coefficient: log Pow: 2.2 at 25 °C noctanol/water Ignition temperature 380 °C at 986.8 - 1,035.9 hPa Method: DIN 51794 Oxidizing properties The substance or mixture is not classified as oxidizing. Molecular weight 130.5 g/mol 37 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works SECTION 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of hazardous Polymerization can occur. reactions Conditions to avoid Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 55 °C. Can form a combustible mixture with air at pressures above atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure. Incompatible materials to Strong oxidizing agents avoid Finely divided magnesium Finely divided aluminium Hazardous decomposition In case of fire hazardous decomposition products may be products produced such as: Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Gaseous hydrogen chloride (HCl). Gaseous hydrogen fluoride (HF) SECTION 11. TOXICOLOGICAL INFORMATIO Acute inhalation toxicity LC50: 120000 ppm Exposure time: 4 h Species: rat Skin irritation Species: rabbit Result: No skin irritation Classification: Not classified as a skin irritant in animal testing. Method: OECD Test Guideline 404 Exposure time: 4 h Sensitisation Result: Does not cause skin sensitisation. Classification: Patch test on human volunteers did not demonstrate sensitisation properties. Cardiac sensitization Species: dogs Note: Cardiac sensitisation threshold (dog): 25000 ppm. Repeated dose toxicity Species: rat Application Route: Inhalation Exposure time: 4 Weeks 38 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works NOEL: 4500 ppm Note: Subacute toxicity Genotoxicity in vitro Test Method: Mutagenicity (Salmonella typhimurium – reverse mutation assay) Result: negative Genotoxicity in vivo Species: rat Cell type: Bone marrow Method: Mutagenicity (micronucleus test) Result: negative Genotoxicity in vivo Test Method: Unscheduled DNA synthesis Species: rat Result: negative Genotoxicity in vivo Species: mouse Cell type: Bone marrow Method: Mutagenicity (micronucleus test) Result: negative Reproductive toxicity Species: rabbit Note: No-observed-effect level - 15,000 ppm Species: rat Note: No-observed-effect level - 10,000 ppm Teratogenicity Species: rabbit Note: No-observed-effect level - 15,000 ppm Species: rat Note: No-observed-effect level - 10,000 ppm Further information Note: Excessive exposure may cause central nervous system effects including drowsiness and dizziness. Excessive exposure may also cause cardiac arrhythmia. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish LC50: 38 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Method: OECD Test Guideline 203 Toxicity to daphnia and Immobilization other aquatic invertebrates EC50: 82 mg/l Exposure time: 48 h 39 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202 Toxicity to algae Growth inhibition EC50: 106.7 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201 Growth rate NOEC: 115 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201 Elimination information (persistence and degradability) Biodegradability Result: Not readily biodegradable. Value: 0 % Method: OECD 301 D Further information on ecology SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Observe all Federal, State, and Local Environmental regulations. Note Where possible recycling is preferred to disposal or incineration. SECTION 14. TRANSPORT INFORMATION DOT UN/ID No. UN 3163 Proper shipping name LIQUEFIED GAS, N.O.S. (Trans-1-Chloro-3,3,3-trifluoropropene) Class 2.2 Packing group Hazard Labels 2.2 IATA UN/ID No. UN 3163 Description of the goods LIQUEFIED GAS, N.O.S. (Trans-1-Chloro-3,3,3-trifluoropropene) Class 2.2 Hazard Labels 2.2 Packing instruction (cargo aircraft) 200 Packing instruction 200 (passenger aircraft) IMDG UN/ID No. UN 3163 40 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Description of the goods LIQUEFIED GAS, N.O.S. (TRANS-1-CHLORO-3,3,3 TRIFLUOROPROPENE) Class 2.2 Hazard Labels 2.2 EmS Number F-C, S-V Marine pollutant no SECTION 15. REGULATORY INFORMATION Inventories US. Toxic Substances Control Act On TSCA Inventory Australia. Industrial On the inventory, or in compliance with the inventory Chemical (Notification and Assessment) Act Canada. Canadian All components of this product are on the Canadian DSL. Environmental Protection Act (CEPA). Domestic Substances List (DSL) Japan. Kashin-Hou Law List On the inventory, or in compliance with the inventory Korea. Toxic Chemical On the inventory, or in compliance with the inventory Control Law (TCCL) List Philippines. The Toxic Not in compliance with the inventory Substances and Hazardous and Nuclear Waste Control Act trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 China. Inventory of Existing On the inventory, or in compliance with the inventory Chemical Substances New Zealand. Inventory of Not in compliance with the inventory Chemicals (NZIoC), as published by ERMA New Zealand trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 National regulatory information SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components SARA 313: This material does not contain any chemical 41 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Acute Health Hazard Sudden Release of Pressure Hazard California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. New Jersey RTK trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 Pennsylvania RTK trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 WHMIS Classification A: Compressed Gas This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR SECTION 16. OTHER INFORMATION HMIS III NFPA Health hazard 2 2 Flammability 0 0 Physical Hazard 0 Instability 0 Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties. Changes since the last version are highlighted in the margin. This version replaces all previous versions. Previous Issue Date: 01/06/2014 Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group 42 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works HFO-1336mz-Z Opteon™ 1100 Foam Expansion Agent Version Revision Date: SDS Number: Date of last issue: 2018/10/17 8.3 2018/12/20 1349835-00039 Date of first issue: 2017/02/27 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Opteon™ 1100 Foam Expansion Agent SDS-Identcode: 130000135541 Manufacturer or supplier's details Company: The Chemours (Thailand) Company Limited Address: Unit 1502, 15th Floor, GPF Witthayu Tower A, 93/1 Wireless Road, Lumpini, Pathumwan, Bangkok 10330, Thailand Telephone: 0 2117 5599 (INT +66 2117 5599) Emergency telephone number: 1800-010-157 Telefax: 0 2117 5572 (INT +66 2117 5572) Recommended use of the chemical and restrictions on use Recommended use: Foam expansion agent Restrictions on use: Consumer use 2. HAZARDS IDENTIFICATION GHS Classification Short-term (acute) aquatic hazard: Category 3 GHS label elements Hazard pictograms: None Signal word: None Hazard statements: H402 Harmful to aquatic life. Precautionary statements: Prevention: P273 Avoid release to the environment. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Misuse or intentional inhalation abuse may cause death without warning symptoms, due to cardiac effects. Rapid evaporation of the product may cause frostbite. 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture: Substance 43 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Substance name: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene CAS-No.: 692-49-9 Components Chemical name CAS-No. Concentration (% w/w) (Z)-1,1,1,4,4,4-Hexafluoro-2- 692-49-9 >= 90 -<= 100 butene* * Voluntarily-disclosed non-hazardous substance 4. FIRST AID MEASURES If inhaled: If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact: Wash with water and soap as a precaution. Get medical attention if symptoms occur. In case of eye contact: Flush eyes with water as a precaution. Get medical attention if irritation develops and persists. If swallowed: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms: May cause cardiac arrhythmia. and effects, both acute and Other symptoms potentially related to misuse or delayed inhalation abuse are Cardiac sensitisation Anaesthetic effects Light-headedness Dizziness confusion Lack of coordination Drowsiness Unconsciousness Protection of first-aiders: No special precautions are necessary for first aid responders. Notes to physician: Treat symptomatically and supportively. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Not applicable Will not burn Unsuitable extinguishing media: Not applicable Will not burn 44 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Specific hazards during firefighting: Exposure to combustion products may be a hazard to health. Hazardous combustion products: Hydrogen fluoride carbonyl fluoride Carbon oxides Specific extinguishing methods: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment: Wear self-contained breathing apparatus for for firefighters firefighting if necessary. Use personal protective equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective: Follow safe handling advice and personal equipment and emergency protective equipment recommendations. procedures Environmental precautions: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for: Soak up with inert absorbent material. containment and cleaning up For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter mine which regulations are applicable. 45 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Sections 13 and 15 of this SDS provide information regarding certain local or national requirements 7. HANDLING AND STORAGE Technical measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation: Use only with adequate ventilation. Advice on safe handling: Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment. Take care to prevent spills, waste and minimize release to the environment. Valve protection caps and valve outlet threaded plugs must remain in place unless container is secured with valve outlet piped to use point. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. Use a pressure reducing regulator when connecting cylinder to lower pressure (<3000 psig) piping or systems. Never attempt to lift cylinder by its cap. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Conditions for safe storage: Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Separate full containers from empty containers. Do not store near combustible materials. Avoid area where salt or other corrosive materials are present. Do not expose drums to direct heat or temperature above 46°C (115°F) to avoid pressurizing and possibly distorting the drums. Material should not be dispensed by pouring from pail/drum shipping containers containing 5 gallons or more. The use of a drum pump is recommended for dispensing from pail/drum shipping containers with 5 gallons or more, except for smaller containers where adequate ventilation can be used to manage the exposure. Keep in properly labelled containers. Store in accordance with the particular national regulations. 46 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Materials to avoid: No special restrictions on storage with other products. Recommended storage temperature: < 46 °C Storage period: > 10 yr Further information on storage stability: The product has an indefinite shelf life when stored properly. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Filter type: Organic gas and low boiling vapour type Hand protection Material: Low temperature resistant gloves Remarks: Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous sub stance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Breakthrough time is not determined for the product. Change gloves often! Eye protection: Wear the following personal protective equipment: Safety glasses Skin and body protection: Skin should be washed after contact. Hygiene measures: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: liquid Colour: clear, colourless Odour: odourless 47 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Odour Threshold: No data available pH: 7.4 (20 °C) Melting point/freezing point: No data available Initial boiling point and Boiling range: 33 °C Flash point: Method: ASTM D 56 boils before flash Evaporation rate: No data available Flammability (solid, gas): Not applicable Flammability (liquids): Will not burn Upper explosion limit/: Upper flammability limit Upper flammability limit Method: ASTM E681 None. Lower explosion limit/: Lower flammability limit Lower flammability limit Method: ASTM E681 None. Vapour pressure: 604.35 hPa (20 °C) Relative vapour density: No data available Density: 1.4 g/cm3 (20 °C) (as liquid) Solubility(ies) Water solubility: 0.7633 g/l (25 °C) Partition coefficient: n: log Pow: 2.3 (30 °C) octanol/water Auto-ignition temperature: No data available Decomposition temperature: No data available Viscosity Viscosity, kinematic: No data available Explosive properties: Not explosive Oxidizing properties: The substance or mixture is not classified as oxidizing. Particle size: Not applicable 10. STABILITY AND REACTIVITY Reactivity: Not classified as a reactivity hazard. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: None known. Conditions to avoid: None known. Incompatible materials: None. Hazardous decomposition products: No hazardous decomposition products are known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of: Inhalation exposure Skin contact 48 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Ingestion Eye contact Acute toxicity Not classified based on available information. Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Acute inhalation toxicity: LC50 (Rat): > 690.413 mg/l Exposure time: 4 h Test atmosphere: vapour Method: OECD Test Guideline 403 No observed adverse effect concentration (Dog): 12500 ppm Test atmosphere: gas Lowest observed adverse effect concentration (Dog): 25000 ppm Test atmosphere: gas Cardiac sensitisation threshold limit (Dog): 1,677,740 mg/m3 Test atmosphere: gas Skin corrosion/irritation Not classified based on available information. Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Genotoxicity in vitro: Test Type: Bacterial reverse mutation assay (AMES) 49 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Method: OECD Test Guideline 471 Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative Genotoxicity in vivo: Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Method: OECD Test Guideline 474 Result: negative Germ cell Mutagenicity: Weight of evidence does not support classification as a Assessment germ cell mutagen. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Effects on fertility Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: inhalation (vapour) Method: OECD Test Guideline 416 Result: negative Effects on foetal Test Type: Embryo-foetal development development Species: Rabbit Application Route: inhalation (vapour) Method: OECD Test Guideline 414 Result: negative Reproductive toxicity – Weight of evidence does not support classification for Assessment reproductive toxicity STOT - single exposure Not classified based on available information. STOT – repeated exposure Not classified based on available information. Repeated dose toxicity Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Species Rat, male NOAEL 33.5 mg/l 50 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Application Route inhalation (vapour) Exposure time 90 Days Method OECD Test Guideline 413 Aspiration toxicity Not classified based on available information. 12. ECOLOGICAL INFORMATION Ecotoxicity Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Toxicity to fish LC50 (Oryzias latipes (Japanese medaka)): 76.1 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and EC50 (Daphnia magna (Water flea)): 22.5 mg/l other aquatic invertebrates Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae ErC50 (Pseudokirchneriella subcapitata (green algae)): > 23.7 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Pseudokirchneriella subcapitata (green algae)): 6.92 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic NOEC (Gobiocypris rarus (rare gudgeon)): 10 mg/l toxicity) Exposure time: 32 d Method: OECD Test Guideline 210 Toxicity to daphnia and NOEC (Daphnia magna (Water flea)): 10 mg/l Other aquatic invertebrates Exposure time: 21 d (Chronic toxicity) Method: OECD Test Guideline 211 Persistence and degradability Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Biodegradability Result: Not readily biodegradable. Bioaccumulative potential Components: (Z)-1,1,1,4,4,4-Hexafluoro-2-butene: Partition coefficient log Pow: 2.3 n-octanol/water 51 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Mobility in soil No data available Other adverse effects Product: Results of PBT and vPvB This substance is not considered to be persistent, assessment bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB) 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Dispose of in accordance with local regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. If not otherwise specified: Dispose of as unused product. 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Hazardous Substance Act B.E. 2535 (Z)-1,1,1,4,4,4-Hexafluoro-2-butene Emergency Decree on Controlling the Use Not applicable of Volatile Substances B.E. 2533 16. OTHER INFORMATION Other information Opteon™ and any associated logos are trademarks or copyrights of The Chemours Company FC, LLC. Chemours™ and the Chemours Logo are trademarks of The Chemours Company. Before use read Chemours safety information. For further information contact the local Chemours office or nominated distributors 52 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works CARBON DIOXIDE (CO2) 1. PRODUCT AND COMPANY IDENTIFICATION Catalogue No 823269 Product name Carbon dioxide for synthesis Manufacturer/supplier identification Company Merck Ltd. 9th Floor, Monterey Tower, 2170 New Petchburi Road, Bangkapi, Huaykwang, Bangkok 10320 Tel: (662) 308 - 0218 2. HAZARDS IDENTIFICATION CAS-No 124-38-9 EC-Index-No - Molar mass 44.01 EINECS-No. 204-696-9 Molecular formula CO2 3. COMPOSITION/INFORMATION ON INGREDIENTS According to the evaluative data available, a classification according to categories of danger as specified in Directive 67/548/EEC and laid down in the legislation of the country concerned is not required. 4. FIRST AID MEASURES After inhalation: fresh air. If necessary, apply mouth-to-mouth resuscitation or mechanical ventilation. If victim is unconscious: lateral recumbent position. 5. FIREFIGHTING MEASURES Suitable extinguishing media: In adaption to materials stored in the immediate neighborhood. Cool containers with water. Other information: Non-combustible. 6. ACCIDENTAL RELEASE MEASURES Stop flow of gas, move leaking cylinder to open air if without risk. 7. HANDLING AND STORAGE Handling: No further requirements. Storage: tightly closed, in a well-ventilated place 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Specific control parameter MAK Germany (max. workplace conc.) Carbon dioxide 5000 ml/m3 or 9100 mg/m3 53 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Personal protective equipment: Respiratory protection: required Eye protection: required Hand protection: required Industrial hygiene: Change contaminated clothing. Application of skin-protective barrier cream recommended. Wash hands after working with substance. 9. PHYSICAL AND CHEMICAL PROPERTIES Form: gas Colour: colourless Odour: slightly sourish pH value not available Melting temperature not available Boiling temperature -79 °C Ignition temperature not available Flash point not available Explosion limits lower not available upper not available Solubility in water (20 °C) slightly soluble 10. STABILITY AND REACTIVITY Conditions to be avoided no information available Substances to be avoided amines, ammonia Hazardous decomposition products no information available 11. TOXICOLOGICAL INFORMATION Acute toxicity Quantitative data on the toxicity of this product are not available. Further toxicological information The literature and our own experience have not revealed any hazardous properties. After uptake of large quantities: headache, Drowziness, dizziness, euphoria, excitation, spasms, in certain circumstances narcosis. 12. ECOLOGICAL INFORMATION No ecological problems are to be expected when the product is handled and used with due care and attention. 54 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 13. DISPOSAL CONSIDERATIONS Product: There are no uniform EC Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste. Packaging: Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non- contaminated packaging may be treated like household waste or recycled. 14. TRANSPORT INFORMATION Transport over land ADR/RID and GGVS/GGVE (Germany) GGVS/GGVE class: 2 Number and letter: ADR/RID class: 2 Number and letter: Name of material: 1013 KOHLENDIOXID River transport ADN/ADNR not examined Sea transport IMDG IMDG class: 2.2 UN-No.: 1013 Packaging group: Ems: 2-09 MFAG: 615 Correct technical name: CARBON DIOXIDE Air transport ICAO-TI and IATA-DGR ICAO/IATA class: 2.2 UN/ID-No.: 1013 Packaging group: Correct technical name: CARBON DIOXIDE The transport regulations are cited according to international regulations and in the form applicable in Germany (GGVS/GGVE). Possible national deviations in other countries are not considered. 15. REGULATORY INFORMATION Labelling according to EC Directives R-phrases: --- S-phrases: S 3-7 Keep in a cool place. Keep container tightly closed. German regulations Water pollution class 0 (generally nonpolluting substance) 16. OTHER INFORMATION no information available 55 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Polyol 1. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifier Trade name: Hilti Firestop Foam CFS-F FX CP 660 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Construction chemicals 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road Trafford Park GB-M17 1BY Manchester Phone: 0800 886 100 (Freephone) Fax: 0800 886 200 (Freefax) Email: gbsales@hilti.com Informing department: chemicals.hse@hilti.com see section 16 1.4 Emergency telephone number: Hilti (Gt. Britain) Ltd Phone: 0800 886 100 (Freephone) Fax: 0800 886 200 (Freefax) Schweizerisches Toxikologisches Informationszentrum - 24 h Service Tel.: 0041 / 44 251 51 51 (international) 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 56 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. Signal word Danger Hazard-determining components of labelling: methylenediphenyl diisocyanate, ethylenediamine, ethoxylated and proxylated Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statements P260 Do not breathe vapours. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Additional information: Contains isocyanates. May produce an allergic reaction. 2.2 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable 3. COMPOSITION/INFORMATION ON INGREDIENTS components: CAS: 26316-40-5 Reg.nr.: 01-2119471488-26 ethylenediamine, ethoxylated and proxylated 57 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works CAS: 25214-63-5 Reg.nr.: 01-2119471485-32 ehylenediamine, ethoxylated 4. FIRST AID MEASURES 4.1 Description of first aid measures General information Instantly remove any clothing soiled by the product. After inhalation Take affected persons into the open air and position comfortably Seek medical treatment in case of complaints. After skin contact Instantly wash with water and soap and rinse thoroughly. If skin irritation persists, call a physician. If skin irritation continues, consult a doctor. After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. After swallowing Seek immediate medical advice. 4.2 Most important symptoms and effects, both acute and delayed Allergic reactions 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing agents Water spray, carbon dioxide (CO2), carbon dioxide blanket, foam, or dry powder. 5.2 Special hazards arising from the substance or mixture Can be released in case of fire Carbon monoxide (CO) Carbon dioxide (CO2) Nitrogen oxides (NOx) 5.3 Advice for firefighters Protective equipment: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Particular danger of slipping on leaked/spilled product. 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. 58 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 6.3 Methods and material for containment and cleaning up: Collect mechanically. Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. 6.4 Reference to other sections See Section 8 for information on personal protection equipment. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Provide sufficient air exchange and/or exhaust in work rooms. When using, do not eat, drink or smoke. Ingestion, exposure to skin and eyes and inhalation of any general vapours should be avoided. 7.2 Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and containers: Keep packaging securely closed and dry, store at 5 °C to 25 °C. Information about storage in one common storage facility: Store away from foodstuffs. Further information about storage conditions: Store in a locked cabinet or with access restricted to technical experts or their assistants. Store container in a well ventilated position. Protect from heat and direct sunlight. · 7.3 Specific end use(s) No further relevant information available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Additional information about design of technical systems: No further data; see item 7. 8.1 Control parameters Components with limit values that require monitoring at the workplace: 9016-87-9 4,4'-diphenylmethanediisocyanate, isomeres and homologues MEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 8.2 Exposure controls Personal protective equipment General protective and hygienic measures The usual precautionary measures should be adhered to general rules for handling chemicals. Do not inhale gases / fumes / aerosols. Wash hands during breaks and at the end of the work. 59 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Keep away from foodstuffs, beverages and food. Avoid contact with the eyes and skin. Breathing equipment: Not necessary if room is well-ventilated. Use breathing protection in case of insufficient ventilation. Protection of hands: Protective gloves EN 374 The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves Synthetic gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed safety glasses. EN 166 + EN 170 Body protection: Protective work clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Red Odour: Characteristic Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined 60 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Flash point: Not applicable Self-inflammability: Product is not selfigniting. Danger of explosion: Product is not explosive. Density Not determined Solubility in / Miscibility with Water: Not miscible or difficult to mix 9.2 Other information No further relevant information available. 10. STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions Reacts with water 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: none, if stored and handled correctly. 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity: 9016-87-9 4,4'-diphenylmethanediisocyanate, isomeres and homologues Oral LD50 >5000 mg/kg (rat) Inhalative LC50/4 h 0.49 mg/l (rat) 26316-40-5 ethylenediamine, ethoxylated and proxylated Oral LD50 >5000 mg/kg (rat) Dermal LD50 >5000 mg/kg (rat) 25214-63-5 ehylenediamine, ethoxylated Oral LD50 >2000 mg/kg (rat) Dermal LD50 >2000 mg/kg (rat) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritant effect. Sensitization: Sensitization possible by skin contact. Sensitization possible by inhalation. 61 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Harmful CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Limited evidence of a carcinogenic effect. Carc. 2 12. ECOLOGICAL INFORMATION 12.1 Toxicity Aquatic toxicity: No further relevant information available. 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. Ecotoxical effects: Not determined Additional ecological information: General notes: Do not allow product to reach ground water, water bodies or sewage system. 12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 12.6 Other adverse effects No further relevant information available. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. European waste catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. Dispose of packaging according to regulations on the disposal of packagings. Empty packs: May be disposed via the local Green Dot collecting system (valpak) or EAK waste material code 150102 (plastic packaging 62 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 14. TRANSPORT INFORMATION 14.1 UN-Number ADR, ADN, IMDG, IATA Void 14.2 UN proper shipping name ADR, ADN, IMDG, IATA Void 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Void 14.4 Packing group ADR, IMDG, IATA Void 14.5 Environmental hazards: Not applicable. 14.6 Special precautions for user Not applicable. 14.7 Transport in bulk according to Not applicable. Annex II of MARPOL73/78 and the IBC Code UN "Model Regulation - 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. 15.2 Chemical safety assessment: not required. 16. OTHER INFORMATION These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure. 63 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ISOCYANATE 1. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name 4,4′-Methylenebis(phenyl isocyanate) Product Number 256439 Brand Aldrich Index-No. 615-005-00-9 REACH No. A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. CAS-No. 101-68-8 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company Sigma-Aldrich Pte Ltd (Co. Registration No. 199403788W) 1 Science Park Road #02-14 The Capricorn, S'pore Sci. PkII SINGAPORE 117528 SINGAPORE Telephone +65 6779-1200 Fax +65 6779-1822 1.4 Emergency telephone number Emergency Phone # 1-800-262-8200 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Inhalation (Category 4), H332 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Respiratory sensitisation (Category 1), H334 Skin sensitisation (Category 1), H317 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure (Category 2), H373 For the full text of the H-Statements mentioned in this Section, see Section 16. 64 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statement(s) P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Supplemental Hazard none Statements 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachry mator. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Synonyms 4,4′-MDI Bis(4-i socyanatophenyl) methane Formula C15H10N2O2 65 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Molecular weight 250,25 g/mol CAS-No. 101-68-8 EC-No. 202-966-0 Index-No. 615-005-00-9 4. FIRST AID MEASURES 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information No data available 66 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature -20 °C Handle and store under inert gas. Moisture sensitive. Heat sensitive. Storage class (TRGS 510): 13: Non-Combustible Solids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). 67 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Full contact Material: Nature latex/chloroprene Minimum layer thickness: 0,6 mm Break through time: 480 min Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 60 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e- mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole 68 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU) 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties a) Appearance Form: crystalline Colour: white b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing Melting point/range: 38 - 42 °C - lit. point f) Initial boiling point and 200 °C at 7 hPa - lit. boiling range g) Flash point 113 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) The product is not flammable. - Flammability (solids) j) Upper/lower No data available flammability or explosive limits k) Vapour pressure No data available l) Vapour density No data available m) Relative density 1,18 g/mL at 25 °C n) Water solubility No data available o) Partition coefficient: No data available n-octanol/water p) Auto-ignition > 601 °C temperature at 1.013 hPa q) Decomposition No data available temperature r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available 10. STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 69 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid No data available 10.5 Incompatible materials Water, Amines, Strong bases, Alcohols 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available. In the event of fire: see section 5 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 9.200 mg/kg Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Ataxia. Nutritional and Gross Metabolic:Changes in:Body temperature decrease. LC50 Inhalation - Rat - male and female - 1 h - > 2,24 mg/l (OECD Test Guideline 403) Skin corrosion/irritation No data available Serious eye damage/eye irritation Eyes - Rabbit Result: Moderate eye irritation Respiratory or skin sensitization in vivo assay - Guinea pig Result: May cause sensitisation by inhalation. in vivo assay - Mouse Result: May cause sensitisation by skin contact. Germ cell mutagenicity Laboratory experiments have shown mutagenic effects. Ames test S. typhimurium Result: negative Mutagenicity (micronucleus test) Rat - male Result: negative 70 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Carcinogenicity This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation. - Respiratory system Specific target organ toxicity - repeated exposure Inhalation - May cause damage to organs through prolonged or repeated exposure. – Respiratory system Aspiration hazard No data available Additional Information RTECS: NQ9350000 Cough, Shortness of breath, Headache, Nausea, Vomiting, Pulmonary edema. Effects may be delayed. 12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 0,35 mg/l - 24 h other aquatic (Diphenylmethane-4,4'- diisocyanate) invertebrates 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential Bioaccumulation Cyprinus carpio (Carp) - 28 d - 0,0008 mg/l(Diphenylmethane-4,4'-diisocyanate) Bioconcentration factor (BCF): 92 12.4 Mobility in soil No data available (Diphenylmethane-4,4'-diisocyanate) 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 71 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 12.6 Other adverse effects Do not empty into drains. No data available 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION 14.1 UN number ADR/RID: - IMDG: - IATA: 3335 14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Aviation regulated solid, n.o.s. (Diphenylmethane-4,4'-diisocyanate) 14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: 9 14.4 Packaging group ADR/RID: - IMDG: - IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out 16. OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. 72 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Further information Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. 73 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works METHYLENE CHLORIDE 1. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name Methylene chloride Product Number M1550000 Brand Sigma-Aldrich REACH No. A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. CAS-No. 75-09-2 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company Sigma-Aldrich Pte Ltd (Co. Registration No. 199403788W) 1 Science Park Road #02-14 The Capricorn, S'pore Sci. PkII SINGAPORE 117528 SINGAPORE Telephone +65 6779-1200 Fax +65 6779-1822 1.4 Emergency telephone number Emergency Phone # : 1-800-262-8200 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure, Oral (Category 2), Liver, Blood, H373 Specific target organ toxicity - repeated exposure, Inhalation (Category 2), Central nervous system, H373 For the full text of the H-Statements mentioned in this Section, see Section 16. 74 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Warning Hazard statement(s) H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs (Liver, Blood) through prolonged or repeated exposure if swallowed. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure if inhaled. Precautionary statement(s) P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulate and toxic (PBT), or very persistent and very bio accumulative (vPvB) at levels of 0.1% or higher 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Formula CH2Cl2 Molecular weight 84.93 g/mol CAS-No. 75-09-2 Hazardous ingredients according to Regulation (EC) No 1272/2008 75 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Component Classification Concentration Methylene chloride CAS-No. 75-09-2 Skin Irrit. 2; Eye Irrit. 2; Carc. <= 100 % EC-No. 200-838-9 2; STOT SE 3; STOT RE 2; Index-No. 602-004-00-3 H315, H319, H351, H336, H335, H373, H373 For the full text of the H-Statements mentioned in this Section, see Section 16 4. FIRST AID MEASURES 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information No data available 76 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Non-Combustible Liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use 77 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engine protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: colourless b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point -97.0 °C f) Initial boiling point and boiling range 40.0 °C at 1,013.2 hPa g) Flash point No data available h) Evaporation rate 0.71 i) Flammability (solid, gas) No data available j) Upper/lower flammability Upper explosion limit: 19 %(V) or explosive limits Lower explosion limit: 12 %(V) k) Vapour pressure 470.9 hPa at 20.0 °C l) Vapour density 2.93 - (Air = 1.0) m) Relative density 1.32 g/cm3 n) Water solubility slightly soluble o) Partition coefficient: log Pow: 1.25 78 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works n-octanol/water p) Auto-ignition temperature 556.1 °C 662.0 °C q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Relative vapour density 2.93 - (Air = 1.0) 10. STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. Exposure to sunlight. 10.5 Incompatible materials Alkali metals, Aluminum, Strong oxidizing agents, Bases, Amines, Magnesium, Strong acids and strong bases, Vinyl compounds 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas In the event of fire: see section 5 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - > 2,000 mg/kg (Methylene chloride) LC50 Inhalation - Rat - 52,000 mg/m3 (Methylene chloride) LD50 Dermal - Rat - > 2,000 mg/kg (Methylene chloride) (OECD Test Guideline 402) Skin corrosion/irritation Skin – Rabbit (Methylene chloride) Result: Irritating to skin. - 24 h (Draize Test) 79 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Serious eye damage/eye irritation Eyes – Rabbit (Methylene chloride) Result: Irritating to eyes. - 24 h (Draize Test) Respiratory or skin sensitisation No data available (Methylene chloride) Germ cell mutagenicity (Methylene chloride) Rat DNA damage Carcinogenicity Limited evidence of carcinogenicity in animal studies (Methylene chloride) Suspected human carcinogens (Methylene chloride) IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available (Methylene chloride) Specific target organ toxicity - single exposure May cause respiratory irritation (Methylene chloride) May cause drowsiness or dizziness (Methylene chloride) Specific target organ toxicity – repeated exposure Inhalation - May cause damage to organs through prolonged or repeated exposure. - Central nervous system Oral - May cause damage to organs through prolonged or repeated exposure. - Liver, Blood Aspiration hazard No data available (Methylene chloride) Additional Information RTECS: Not available Dichloromethane is metabolized in the body producing carbon monoxide which blood, reducing the oxygen-carrying capacity of the blood., Acts as a simple asphyxiant by displacing air., anesthetic effects, Difficulty in breathing, Headache, Dizziness, Prolonged or repeated contact with skin may cause:, defatting, Dermatitis, Contact with eyes can cause:, Redness, Blurred vision, Provokes tears., Effects due to ingestion may include:, Gastrointestinal discomfort, Central nervous system depression, Paresthesia., Drowsiness, Convulsions, Conjunctivitis., Pulmonary edema. Effects may be delayed., Irregular 80 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works breathing., Stomach/intestinal disorders, Nausea, Vomiting, Increased liver enzymes., Weakness, Heavy or prolonged skin exposure may result in the absorption of harmful amounts of material., Abdominal pain (Methylene chloride) To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. (Methylene chloride) 12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) 193.00 mg/l - 96 h (Methylene chloride) NOEC - Cyprinodon variegatus (sheepshead minnow) 130 mg/l – 96 h (Methylene chloride) Toxicity to daphnia and EC50 - Daphnia magna (Water flea) other aquatic invertebrates 1,682.00 mg/l - 48 h (Methylene chloride) 12.2 Persistence and degradability Biodegradability Result: < 26 % - Not readily biodegradable. (OECD Test Guideline 301C) 12.3 Bioaccumulative potential Does not bioaccumulate. 12.4 Mobility in soil No data available (Methylene chloride) 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION 14.1 UN number ADR/RID: IMDG: IATA: 14.2 UN proper shipping name ADR/RID: IMDG: IATA: 81 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 14.3 Transport hazard class(es) ADR/RID: IMDG: IATA: 14.4 Packaging group ADR/RID: IMDG: IATA: 14.5 Environmental hazards ADR/RID: IMDG Marine pollutant: IATA: 14.6 Special precautions for user No data available 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out 16. OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure if inhaled. Further information Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. 82 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX C Personal Protective Equipment for spraying foam Protective clothing 1) Appropriate clothing to prevent chemical contact 2) Dispose the protective clothing after work to prevent the chemical exposure to the skin 3) Wear protective cloth to prevent chemical contact to skin Respirators Chemical aerosol of isocyanate in the air may exceed Occupational Exposure Limits for a sprayer and assistance working close to the equipment. Moreover, the aerosol of the catalyst (amine) and blowing agent can be found at high concentration. Indoor foam spraying generates more aerosol than outdoor foam spraying. Air supplied respirator is needed for indoor foam spraying; however, air purifying mask is safe enough for outdoor foam spraying. Full-faced with air supplied respirator is needed for confined space. Chemical protective clothing Chemical protective clothing with a respirator is designed to protect worker from chemical exposure at normal working conditions. Safety goggles Goggles help prevent the chemical splash into the eyes and prevent the particulate from foam trimming. The PPE includes safety goggles, full-faced mask. Contact lenses are not recommend at work. Gloves Nitrile, Neoprene PVC gloves are safe enough to protect the skin from isocyanate and polyols. These types of gloves help protect workers’ skin from chemicals and heat from tubing. Use the proper size of the gloves when spraying Figure 8-1 chemical respirator Figure 8-2 protective clothing Figure 8-3 Safety goggles Figure 8-3 Chemical gloves 83 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX D Chemical management Chemical management and storage • Proper storage is important before and during foam spraying. Improper storage may affect the performance of the chemicals. • Store polyol and isocyanate drum in cool and dry area following manufacturers’ SDS. The chemical drum should be sealed to prevent the contamination. • Prevent isocyanate drum from moisture or water. Water can react with isocyanate to generate carbon dioxide resulting in high pressure in a drum. • Do not overlay isocyanate drums more than 3 layers, and prevent from heat and direct sunlight first aid measures in case of chemical exposure If inhale - Stay away from aerosols of polyol and isocyanate all the time - Evacuate from the area and see a doctor If skin contact - wash with soap and water to rinse off the skin, dispose the contaminated clothing - In case of wound from high pressure of chemicals, see a doctor immediately If eye contact - Eye wash at least 10-15 minutes with plenty of warm water after that use eye patch and see a doctor immediately - No contact lenses when spraying If swallow - Not recommend to vomit, see a doctor immediately 84 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX E Environmental Management Plan: EMP The enterprises, who want to join the HCFC phase-out program, need to prepare Environmental Management Plan and follow their existing standard operating procedure, which will be evaluated by the project management unit. The enterprises may use/fill out the form below with the information and submit to the project management unit. Suggestion Please fill out the form and submit to the project management unit (PMU) including the general information i.e. map and technical information During the program, the contact person should supervise and sign with date to confirm that the company will comply and follow all the rules and regulations. After sign, please submit the form to the project management unit 85 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Environmental Management Plan for HCFC phase-out project Part 1 Enterprise information 1.1 Business name............................................................................................................................................................... Corporate registration number (if available) ................................................................................................................. Website ....................................................................... Product/Service ....................................................................... Plant registration number (if available) ........................................................................................................................ Address Number....................................................................... Street address................................................................... City................................................ Province......................................................... Postcode................................... Telephone......................................................................... Fax ............................................................................................ Contact person name ....................................................................position........................................................................ Telephone................................................... E-mail…….................………………………………………………………………………… 1.2 Business type ☐ Ordinary person ☐ Ordinary Partnership ☐ Limited partnership ☐ Company limited ☐ Other (Please specify) .................................................................... 1.3 General 1. Type of the business information ☐ Spraying foam producer ☐ Foam spraying 2. Business area ☐ Residential area mixed with commercial area ☐ Commercial area ☐ Industrial area 3. Employee number (persons) ☐  5 ☐ 6 - 30 ☐ 31 – 50 ☐ 51 – 200 ☐ > 200 persons 4. Enterprise income ☐ < 10 MB ☐ 10 - 50 MB ☐ 51 – 100 MB ☐ > 100 MB 1.4 Blowing agent ☐ HCFC-141b ☐ HFO-1233zd ☐ HFO-1336mzz-Z used ☐ Other (please identify) .......................................................................................................... 1.6 Area type ☐ storage area (....................m2) ☐ Average area for spraying foam (.................m2 / time) 1.7 Maximum ☐ HCFC-141b .....................................................kg storage/time (kg) ☐ Pre-blend ……………………………………………… kg ☐ MDI ……………………………………………… kg Part 2 General information for spraying foam 2.1 General information for spraying foam Equipment Brand information Type (pressure) Number 2.2 Volume of 2016 2017 2018 HCFC-141b and HCFC-141b HCFC-141b HCFC-141b pre-blend (kg) (100%) (100%) (100%) Pre-blend Pre-blend Pre-blend (..........% HCFC-141b) (..........% HCFC-141b) (..........% HCFC-141b) 86 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Part 2 General information for spraying foam (continued) 2.3 Type of work Risk type Measure for risk control Storage area ☐ Chemical spills ☐ Yes – Attachment 05 ☐ No ☐ Fire ☐ Yes – Attachment 05 ☐ No ☐ Chemical storage ☐ Yes – Attachment 06 ☐ No ☐ Other e.g. waste management, etc. (Please specify) ☐ Yes – Attachment 09 ☐ No ............................................................ Spraying foam ☐ Chemical spills ☐ Yes – Attachment 05 ☐ No area ☐ Work at Height ☐ Yes – Attachment 07 ☐ No ☐ Confined space ☐ Yes – Attachment 08 ☐ No ☐ Other e.g. waste management, etc. (Please specify) ☐ Yes – Attachment 09 ☐ No ............................................................ Part 3 Other Attachment Business information Attachment 01 - Role, responsibility, Time table for the progress and progress report (1 time before the program close) Map of the plant and surrounding (photo attachment) Attachment 02 Map of storage area of HCFC-141b / Pre-blend / MDI (photo attachment) Attachment 03 Standard Operating Procedure after HCFC phase-out Attachment 04 - Checking equipment, pump, spray gun, tubing before and after use - Maintenance of equipment and PPE - Chemical safety training Safety measure after accident Attachment 05 Safety measure for chemical storage Attachment 06 Safety measure for work at height Attachment 07 Safety measure for confined space Attachment 08 Other safety or environmental management measure (if available) Attachment 09 Note: If the form cannot be completed, please provide more relevant attachment Signature___________________________ (________________________________) Position* ______________________________ * The manager or the person responsible for the sub-project operation 87 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 01 General information of the business Business name ........................................................................................................................ ............................... Corporate registration number (if available) ................................................................................................... Website ......................................................... ................ Product/Service............................................................ Plant registration number (if available) ............................................................................................................ Address Number....................................................................... Street address.................................................... City......................................................... Province............................... Postcode................................... Telephone......................................................................... Fax ................................................................ Contact person name ....................................................................position....................................................... Telephone................................................... E-mail……............................………………….……………………… Responsibility (See the details in 11.1) 1. Before conversion: (Please specify the details) .............................................................................................................................................................................. ...... .............................................................................................................................................................................. ...... .................................................................................................................................................................................... 2. After start of production: (Please specify the details) .............................................................................................................................................................................. ...... .............................................................................................................................................................................. ...... .................................................................................................................................................................................... Time table for the progress Activity Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Progress report submission EMP (within 6 months after signed the contract) dd/mm/yy................................................................ ...................................................................... .......................... 88 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 02 Map of Enterprise location Map of Enterprise location (GPS) Photos of Enterprise and surrounding areas (North) 89 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Photos of Enterprise and surrounding areas (South) Photos of Enterprise and surrounding areas (East) 90 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Photos of Enterprise and surrounding areas (West) 91 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 03 Map of chemical storage areas Map of chemical storage areas Figure 1 Photos of chemical storage areas 92 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Figure 2 Photos of chemical storage areas Figure 3 Photos of chemical storage areas 93 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 04 Standard procedures for work after replacement of substitutes Implementation1 Briefly describe Check list Yes No suggestion/difficulty/action required)2 1. Inspection of spraying equipment before and after use - Checking for leakage or damage of chemical pipes. - The condition of the air tank system is checked. - The condition of the electrical wiring of the equipment is checked. - With grounding or proper deposit. - Check the availability of foam spray guns. 2. Provision and maintenance of equipment / PPE - There are maintenance tools according to the instruction manual. - PPEs are provided - Maintenance of PPE according to usage instructions 3. Safety training in working with chemicals - There are chemical storage training. - There are chemical usage training. - There are training on the disposal of used chemicals. 1,2 To be filled up during EMP Monitoring Period and submit to PMU and GSB within 6 months after sub-grant signing 94 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 05 Emergency safety measures If an emergency occurs during foam spraying, the operator should know that how to behave and must know who to contact to help limit damage and harm to workers and the environment. This section discusses how to proceed when an emergency, including people who have to deal with leakage management, to minimize environmental hazards, information about fire safety, and first aid. 1. Emergency contact number Contact information that employees should know is as follows. 1.1 Company owner number and employer number 1.2 Urgency Alert Center 191 1.3 Fire center 199 1.4 Emergency illness notification center 1669 1.5 Department of Disaster Prevention and Mitigation Hotline 1784 2. When a chemical leak occurs When large amounts of chemicals are spilled into the environment, contact the emergency numbers above. If a small number of spills occur in the following actions. - Evacuate those in the accident area from the area. - When having to go to clean the scene, the worker must wear appropriate safety protection equipment - Restricting the spread of chemicals such as dams or using absorbents etc. - To scoop and collect the waste that occurred in the tank to be used to eliminate it properly. 3. When a fire occurs To assess the severity of the fire incident. If the intensity is not large, bring a fire extinguisher type A B C and fire extinguishing foam to suppress fire. If it is a severe case, evacuate the area as quickly and safely as possible and inform the fire center. 4. First aid Should provide a first aid kit in the work area at all times. 95 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 06 Chemical storage inspection form Implementation1 Briefly describe Check list Yes No suggestion/difficulty/action required)2 1. Store all chemicals in a shade, not directly expose to sunlight and far away from heat 2. Store the chemicals in dry area 3. There is enough ventilation in the storage area. 4. Inspect the leakage regularly for the chemical containers. 5. Make safety data sheet (SDS) available and accessible all the time 6. There is an emergency spill kit in the storage area. 1,2 To be filled up during EMP Monitoring Period and submit to PMU and GSB within 6 months after sub-grant signing 96 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 07 Work at height inspection form Implementation1 Briefly describe Check list Yes No suggestion/difficulty/action required)2 1. Provide scaffolding, climbing stairs or safe trusses in the case of working in the ground or building floor from 1.80 meters or more. 2. Create a barrier or fence in the event of working in an open floor or building and may fall. 3. Establish rules for the use of scaffolding, ladder or trestle safely. 4. There is enough space for work on scaffolding, ladder or trestle. 5. The structure of scaffolding, ladder or trestle is strong and safe. 6. Provide protection against splashes or dropping of materials by using a mesh, canvas or any other material that has the same characteristics, blocking or supporting. 1,2 To be filled up during EMP Monitoring Period and submit to PMU and GSB within 6 months after sub-grant signing 97 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Attachment 08 Safety measures for working in confined spaces Implementation1 Briefly describe Check list Yes No suggestion/difficulty/action required)2 Work in confined spaces - Compliance with laws relating to working in confined spaces Working under the roof - The ceiling is opened or the roof is opened to increase ventilation. - With the use of ventilation fans. - There are periodic shuffle of operators. 1,2 To be filled up during EMP Monitoring Period and submit to PMU and GSB within 6 months after sub-grant signing 98 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works ANNEX F Minutes of meeting, listening and commenting Minutes of meeting, listening and commenting “Environment Management Framework (EMF) Project for Spray Foam Sector” Wednesday 19 June 2019 at 12.30 - 4.00 PM. At Meeting Room 503, 5th Floor, Department of Industrial Works Building, Bangkok Participants: 1. Rattana Ruktrakul Director of hazardous substances management division (Chair) 2. Naratip Lauhatirananda Acting expert scientist 3. Visitsak Krissanapant Specialized electrical engineer 4. Natawan Sukchai Specialized scientist 5. Jirodom Turitakom Specialized scientist 6. Khwanlak Kanharat Specialized scientist 7. Asst. Prof. Dr. Amarin Kongtawelert Mahidol University 8. Asst. Prof. Dr. Preecha Loosereevanich Mahidol University 9. Dr. Sumate Pengpumkiat Mahidol University 10. Saowarot Phuaphonthep Mahidol University 11. Rattanyu Detchicharuwat World Bank 12. Phongnarin Phetchu Chem-Safe Consultants Co. Ltd 13. Hattaya Tiangtranont Chem-Safe Consultants Co. Ltd 14. Akarin Wangrit Chem-Safe Consultants Co. Ltd 15. Nucharee Jongsomboonphokha S.P. Insulation Co. Ltd 16. Sawit Injampa S.P. Insulation Co. Ltd 17. Umphika Surakitsamrit Bangkok Insulate Co. Ltd 18. Somchat Surakitsamrit Bangkok Insulate Co. Ltd 19. Anuwat Phatikkulrangsan Dabco Intertrade Co. Ltd 20. Wanlapa Suteewon Spec Engineering Co. Ltd 21. Hans Lohr Lohr Trade and Consulting Co. Ltd 22. Karl-Heinz Martin Lohr Lohr Trade and Consulting Co. Ltd 23. Woraphan Techaworawat South City Petrochem Co. Ltd 24. Prin Phutisombut South City Petrochem Co. Ltd (Chair of Polyurethanes Industry) 25. Sirinath Wongpatham Polyurethanes Industry 26. Jamnong Khueankaew New Tech and J Service Co. Ltd 27. Aphidach Inthanai New Tech and J Service Co. Ltd 28. Siriluk Ngammee Dow Chemical Thailand Co. Ltd 99 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 29. ChetChai Norasetthisrisuk PU Foam Insulation & Trading Co. Ltd 30. Punjama Senaphithak First Mega Tech Co. Ltd 31. Decha Sriyong First Mega Tech จำกัด 32. Athit Somthawin Bangkok Integrated Trading Co. Ltd 33. Thitinan Phomphichan Bangkok Integrated Trading Co. Ltd 34. Wirongrong Phaosang Balmoral Co. Ltd 35. Kiatchai Atsawajitboon Thai Mitsui Specialty Chemicals Co. Ltd 36. Yutthaphong Kanokthanapa Jebsen & Jessen Technology (T) Co. Ltd Opening Time 01.30 PM. The chairperson made an announcement to start the meeting/public hearing. The purposes of the meeting include; 1 . To present the Environmental Management Framework (EMF) HCFC Phase-out project (replacement of HCFC-141b to HFO-1233zd, HFO-1336mz-Z and CO2 in spray foam sector) to the public. 2. To obtain public hearing against the EMF and the EMP. The consultant team (Asst. Prof. Dr. Amarin Kongtawelert) presented the Environmental Management Framework (EMF) HCFC Phase-out project. The main topics include; - Rationale and objectives of the project - Literature review for the chemical substitutes - World Bank Safeguards Policies - The objectives of the EMF - Chemical process for polyurethane spray foam - Schematic diagram of PU foam spraying unit with HFO - Ozone Depletion Potential (ODP) and Global Warming Potential (GWP) for several blowing agents - Physical and chemical properties of blowing agents - Environmental and OHS impacts - Mitigation Measures - Law and regulations regarding to the substitutes - Field survey - Personal Protective Equipment - Chemical storage - First aid - Roles and responsibilities to implement EMF - Institutional arrangement - Grievance Mechanism The consultant proposed the EMP and explained how to complete the plan and forms, examples of the plan, attachment forms and open the floor for public hearing. 100 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works Feedback voiced by the participants and stakeholder 1. Attachment No.04 should be grouped into categories, such as checklist for equipment, maintenance for equipment/PPE and training topics for chemical safety. 2 . SOP for limited oxygen area should be classified into two types; confined space and area under the roof. 3. If workers need to spray PU foam in a confined space i.e. silo, they need to be trained in a course of “confined space” from their employers and the workers need to strictly comply with the law. In a case of the area under the roof, the workers have to open-up the roof or ceiling and use air ventilators. The workers also need to do work shift in every 20-30 minutes. 4 . Most of the foam spraying is made under the roof. The aerosol foam can directly damage chemical cartridge respirator and safety goggles. In practical, the workers use clear plastic bag covering their head to prevent the mask and goggles from the adsorption of foam. 5. Chemical protective clothing, which is available in the market, is not practical suitable in Thailand due to the hot weather. Long-sleeve shirts and long pants with thin fabrics should be worn during working instead of thick protective clothing. 6. The participants and stakeholders called on World Bank to set rules and regulations for the enterprises to follow, and financially support for all relevant the trainings, PPE, oxygen meter, and supplied air respirators for confined space and area under the roof. Closing Time 03:30 PM. 101 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works 102 Environment Management Framework (EMF) Spray Foam Sector Department of industrial works References 1. Environmental management framework. HCFC phase-out project polyurethane foam sector – stage 1 2. Carlos Mateu-Royo*, Joaquín Navarro-Esbrí, Adrián Mota-Babiloni, Marta Amat-Albuixech, and Francisco Molés. Thermodynamic analysis of low GWP alternatives to HFC-245fa in high-temperature heat pumps: HCFO-1224yd(Z), HCFO-1233zd(E) and HFO-1336mzz(Z). 2019; 152:762-77 3. Lists of enterprises from the World Bank 4. World Bank. (1999). Operational Manual OP 4.01 – Environmental Assessment. Available from: https://policies.worldbank.org/sites/ppf3/PPFDocuments/090224b0822f7384.pdf 5. International Finance Corporation. (2016). Environment, Health, and Safety Guidelines. Available from: https://www.ifc.org/wps/wcm/connect/554e8d80488658e4b76af76a6515bb18/Final+- +General+EHS+Guidelines.pdf?MOD=AJPERES 6. Safety data sheet HFO-1233zd; Honeywell International Inc. 7. Safety data sheet HFO-1336mzz-Z; The Chemours (Thailand) Company Limited 8. Safety data sheet Polyol; Hilti (Gt. Britain) Ltd. 9. Safety data sheet Isocyanate; Sigma-Aldrich Pte Ltd 10. Safety data sheet Methylene chloride; Sigma-Aldrich Pte Ltd 103